A moving and storage truck was photographed outside the seven-bedroom, nine-bathroom house by X-17online on Wednesday afternoon.
Tom will keep the mansion, which features a movie theater, tennis court and swimming pool, while Katie will get their Montecito, Calif. home.
As RadarOnline.com first reported, Tom and Katie plan on taking their daughter Suri to school together for the first day at the end of the month.
"Tom has been filming his latest movie in London but has made plans to be in New York for Suri's first day of school, which will be after Labor Day," a source close to the former couple told RadarOnline.com.
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"Tom and Katie have been speaking on the telephone regarding Suri and Katie has been very supportive of Tom wanting to be there when Suri goes to her new school for the first time."