Lesbian Affairs, Blood Vials & More! Angie's Most Scandalous Relationships EXPOSED

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Sep. 22 2016, Updated 9:34 a.m. ET

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brad pitt angelina jolie divorce failed relationships
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Angelina Jolie and Brad Pitt are divorcing after just two years of marriage, but the Salt star isn't a stranger to heartbreak! Click through these 12 slides to see all of Jolie's failed relationships!

The 56th Annual Golden Globe Awards – Miramax After Party

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Jolie, 41, met Johnny Lee Miller on the set of Hackers in 1995. They eloped in 1996, and Jolie later sported a shirt with his name written in her blood.

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Jonny Lee Miller And Angelina Jolie In ‘Hackers’

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The couple divorced in 1999, but Jolie later told Buzzfeed that he is "still a great friend."

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brad pitt angelina jolie divorce failed relationships

Jolie struck up a friendship with Jenny Shimizu on the set of Foxfire in 1996, and became romantically involved with her shortly after. "I would probably have married Jenny if I hadn't married my husband," Jolie said at the time. "I fell in love with her the first second I saw her."

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DKNY – Backstage – Fall 2010 MBFW

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Shimizu later stated that their on-again-off-again relationship lasted for years.

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Ron Galella Archive – File Photos 2010

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Then, the Girl, Interrupted star was pictured kissing her brother, James Haven, at the Golden Globes and the Academy Awards in 2000.

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Ron Galella Archive – File Photos 2010

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She announced that she was "so in love with her brother" during her Academy Awards acceptance speech.

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Angelina Jolie and Billy Bob Thorton At Tomb Raider Premiere

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The actress married Billy Bob Thornton on May 5, 2000 after dating for two months. They infamously talked about their wild sex life during red carpet appearances, and even wore each other's blood in vials around their necks!

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“Original Sin” premieres in LA

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But, the couple couldn't make their relationship work and their divorce was finalized on May 27, 2003.

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AFI FEST 2015 Presented By Audi Opening Night Gala Premiere Of Universal Pictures’ “By the Sea” – Arrivals

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Jolie then began dating Pitt after meeting on the set of Mr. & Mrs. Smith in 2005. Pitt was married to Jennifer Aniston at the time, but they divorced later that year.

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15th Annual AFI Awards Luncheon – Reception

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Pitt adopted Jolie's two children, Maddox and Zahara, shortly after. They welcomed their daughter Shiloh in 2006 and twins Knox and Vivienne in 2008.

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86th Annual Academy Awards – Arrivals

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The couple married in 2014, and Jolie filed for divorce on September 19, 2016.

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“Maleficent” Costume And Props Private Reception – Red Carpet Arrivals

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Stay with Radar for more on Jolie's love life.

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