PHOTOS: Jessica Biel Shines on Red Carpet At Valentine's Day Premiere

Feb. 9 2010, Published 10:03 a.m. ET

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Jessica Biel was the vision of beauty on the Grauman's Chinese Theater as she shined on the red carpet in Hollywood Monday night, where she attended the premiere of her new film, Valentine's Day.

The 27-year-old stunner was clad in a one-shoulder, Oscar de la Renta dress with pink chiffons, the fashion highlight of a star-studded affair that featured appearances by other starlets in the film's ensemble cast, including Anne Hathaway, Demi Moore and Jessica Alba.

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VIDEO: Jessica Biel Eats Chocolate-Covered Cricket

Biel's dress complemented her sculpted figure well, as the actress looked in her usual great shape, and with good reason: Last month, she climbed 19,340 feet up Africa's Mount Kilimanjaro, reaching its' highest peak January 12, after six days of traveling through rough terrain and a nasty blizzard. The climb was to raise awareness for global water crisis advocacy group Summit on the Summit.

Jessica Biel Climbs Mt. Kilimanjaro

Valentine's Day opens Friday.


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