Smooch! Hillary Duff & Penn Badgley Lock Lips On Gossip Girl

Aug. 27 2009, Published 11:53 a.m. ET

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Ooh La La! Hillary Duff and Penn Badgley heat things up on the set of Gossip Girl.

Hillary Duff & Penn Badgley on-set of Gossip Girl: See more photos!

In a scenario where Duff will play Olivia Burke, a movie star looking for the real college experience, Hilary’s character will choose to go to New York University where (surprise) Blair (Leighton Meester), Dan (Penn Badgley) and Vanessa (Jessica Szohr) will also be attending.

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Looks like she has no trouble getting along with Dan, but will she be able to deal with Vanessa, her appointed roommate?

Hillary has signed on for several episodes of the popular teen drama, her first appearance will air on October 5th on the CW.

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