In 2005 Angelina turned it out leather glam in a halter Versace leather gown at the Mr. and Mrs. Smith Los Angeles premiere.

Jolie matched her Sling-Blade man Billy Bob Thornton in leather pants showcasing her branded ink and pulling off the look of a rockstar wife!

Never outgrowing leather pants, Angelina teamed her leather pants with a classy getup and peep-toe pumps at the Beowulf premiere in London. As an A-lister, Jolie dons leather in an upscale classy way!

In 2001, Angelina Jolie attended the Los Angeles premiere of Lara Croft Tomb Raider looking tough in black leather pants, a low-slung belt, and a midriff tattoo exposing tank. Just like her character — the actress looked unstoppable!

Angelina Jolie stole the red carpet show at the LA premiere of Inglourious Basterds in a black leather Michael Kors strapless dress complete with small pockets. Showing off her new honey-touched hair and wearing minimal makeup, Mrs. Jolie Pitt proves that she is a natural beauty, especially in this body-hugging number!