5. Madonna – The Material Girl has always been open about her sexuality but caused jaws to drop when she gave both Christina Aguilera and Britney Spears an open-mouth kiss at the 2003 MTV Movie Awards. Angelina Jolie’s former lover Jenny Shimizu also claimed to have bedded Madonna saying they both “got incredibly turned on by the touch of another woman.” 7. Angelina Jolie – Although loved up now with fiance Brad Pitt and six kids, Angelina was once madly in love with Jenny Shimizu whom she had a long term affair with in her 20s.
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