1986: Years before she was an award winning actress and mother of six, 10-year-old Angelina Jolie got dressed up and made her red carpet debut like a true lady, at an event with father Jon Voight and brother James Haven.

1999: Angelina looked like a Greek goddess in this cream off the shoulder gown at the SAG Awards, where she took home the Best Actress award for her role in GIA.

2000: With father Jon Voight and brother, James Haven; Angie showed off her western style in denim jeans and a tight white tank top.

2000: Angelina graced the red carpet at the Academy Awards in a sheer black gown paired with a matching shawl and pumps, scooping up the award for Best Supporting Actress Award for Girl Interrupted.

2000: Angelina showed her dark side in this black Versace gown at the Academy Awards, channeling Elvira. Later in the evening, she shared her very controversial smooch with brother James Haven.

2000: Angelina revealed her bad girl style at the Gone in 60 Seconds premiere in a tight gray t-shirt and leather pants baring her new Billy Bob ink on her arm, with then husband Thornton.

2001: Angelina rocked a tuxedo-style white satin suit by Dolce and Gabbana at the Academy Awards, breaking away from the traditional gown.

Angelina Jolie at the premiere of her new movie Lara Croft Tomb Raider
6/11/01

The Los Angeles premiere of “Original Sin” at the Directors Guild Theater.

07/31/01

2003: Angie showed off her curves in a sexy low cut gown at the London Premiere of Lara Croft Tomb Raider: The Cradle of Life.

2004: Looking soft and sophisticated in a floral print dress, Angelina attended the 11th Annual Premiere Women in Hollywood Luncheon .

2005: At the UK premiere of Alexander Angie looked professionally pretty, posing for pics with rumored onset beau Colin Farrell and director Oliver Stone.

2005: Brad and Angie hit ShoWest in Las Vegas to promote Mr. and Mrs. Smith amidst a slew of rumor that they hooked up on set. Angie looked gorgeous in a colorful dress.

2005: Back in leather at the Mr. & Mrs. Smith Premiere.

2005: The charitably chic star showed off her assets at the Worldwide Orphans Foundation’s First Benefit Gala in NYC, wearing a gorgeously sparkling nude gown, which was sashed in black.

2006: At the Cannes Film Festival premiere of Ocean’s 13, Angie looked anything but mellow in a gorgeous yellow Emanuel Ungaro gown.

2007: At the Golden Globes, the Mighty Heart actress looked gorgeous in a grey St. John gown.

2007: At the UK premiere of Beowulf, Angelina resurrected her leather pants, which she simply paired with a tight sweater and Christian Louboutin peep-toes.

2008: Angelina tried to conceal her baby bump at the SAG Awards under a neutrally toned vintage Hermes gown. She wasn’t foolin’ anyone!

2008: Angie was an Independent Spirit at the annual awards show in Los Angeles, showing off her new baby bump in a Western Costume flutter-sleeve gown, which she paired with Christian Louboutin heels.

2008: At the Cannes Film Festival premiere of Kung Fu Panda, then-preggers Angie looked gorgeous in a green Max Azria Atelier gown, which flaunted her baby bump.

2008: Brad and Angie dominated at the Los Angeles Premiere of The Curious Case of Benjamin Button, where the actress rocked a velvet strapless Versace gown.

2009: Angelina stunned at the Critics Choice Awards, wearing a one-sleeved Max Azria Spring 2009 gown, which was dramatically slit up the side.

2009: Angie opted to wear her gorgeously blue Max Azria Spring 2009 dress backwards to the SAG Awards.

2009: At the BAFTA Awards, Angie looked unusually edgy in a neon yellow and black Armani Prive Spring 2009 Couture strapless

2009: Adding green Lorraine Schwartz earrings to her sweetheart strapless Elie Saab gown, made all the difference for Angie at the 2009 Academy Awards.

2009: At the Cannes Film Festival premiere of Inglourious Basterds, Angelina smoldered in a nude chiffon one-sleeved Versace gown from the Fall 2008 collection.

2009: Supporting Brad at the Los Angeles premiere of Inglourious Basterds, Angie dropped jaws when she stepped onto the carpet in this black leather Michael Kors Fall 2009 strapless. The dress sold out almost immediately after Angie rocked it in flawless fashion with Christian Dior heels, and was imitated by the droves.

2010: At the Los Angeles premiere of Salt, Angelina dominated the red carpet in simply glam style. The leading lady paired a sequined Emporio Armani strapless with nude Ferragamo pumps, accessorizing only with an Asprey diamond bangle and stud earrings.