Gwyneth added some edge to her look with a Rick Owens biker jacket.

The back of Gwyn’s dress featured a black panel.

Gwyneth looked gorgeous in a dress from pal Victoria Beckham’s line. The
shimmery, gold mini from the Fall 2010 collection featured black side tabs.
She carried a Christian Louboutin Pharaon clutch in her hands.

Gwyn looked gorgeous, wearing her hair loose.

Madonna looked glamorous in a black trench, which featured gold hardware and
exaggerated shoulders.

Her hair was parted down the side, tumbling in curls.

Lourdes Leon had a little red carpet fun, pairing a tribal print,
embellished mini with a biker jacket, ripped nylons and combat boots.

It is unclear what Melissa George was thinking when she wore this beret on
the red carpet, but it is a shame. Her black dress simply stunning and
paired with those glitter heels she was definitely slated as a Best Dressed
contender.

Why, Melissa?

Krysten Ritter looked super sexy in skillfully cut LBD, which featured
exaggerated shoulders. She carried a Rebecca Minkoff “Easy Rider” Date
Clutch.

Hilary Rhoda jazzed up her eggplant mini with strappy, embellished sandals
and an envelope clutch.

Kelly Bensimon kept it simply sexy in skintight LBD, elongated her super tan
legs in plastic heels.

Heather Graham looked gorgeous in a L’Wren Scott Spring 2010 dress, which
looked like it was made for her. She paired the floral etched, curve
hugging number with a glittery clutch and fuchsia, peep-toed heels.