As RadarOnline.com was the first to report, the wedding was set for Big Sur, California with the bride wearing a Valentino original for her big day.
The gown was befitting the actress who shot to fame a decade ago in The Princess Diaries.
PHOTOS: Anne Hathaway Marries Adam Shulman
It was a flowing and deeply romantic off-the-shoulder, vintage-inspired creation. She paired it with white shoes.
Adam, an actor and jewelry designer, was dashing in a classic tuxedo.
The ceremony took place at a private estate with about 150 family and friends in attendance.
They stayed at the nearby Post Ranch Inn and the Ventana Inn & Spa which was where the rehearsal dinner was held Friday night.
Congratulations to them both!